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Shiny Pet Charmer
Earned 500 Shiny Pet Charms before they were replaced by Polished Pet Charms.
Shiny Pet Charmer requires you to accumulate 500 
Shiny Pet Charms in your inventory at one time, earned through daily Garrison pet battle activities in Draenor.
Unlock Garrison Menagerie Daily
Horde players speak to Serr'ah and Alliance players speak to Lio the Lioness to access the Garrison pet daily, which requires a Level 2 Garrison and completion of Pets Versus Pests. Once unlocked, completing Mastering the Menagerie awards the 
Big Bag of Pet Supplies containing 8–10 Shiny Pet Charms, otherwise the daily awards 8 Shiny Pet Charms.
Defeat Six Draenor Tamers
Defeat all six Draenor pet tamers each day, as each tamer awards 4 Shiny Pet Charms per win, totaling 24 Shiny Pet Charms from tamers alone, giving a combined maximum of 32–34 Shiny Pet Charms per character per day.
Hoard Charms Until 500
Do not spend your Shiny Pet Charms, as the achievement tracks only the number currently in your inventory; at this rate it takes approximately 15–16 days of daily farming to reach 500. Shiny Pet Charms mailed from alts on the same account will also count toward the total after you relog.
Tips
This achievement tracks per character by default, but sending Shiny Pet Charms from alts to your main and then relogging will add those charms to your main's achievement counter.
The achievement counter reflects only what is currently in your bags, so reaching 500 held at once is required — spending charms will lower your progress.