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Take Them Out
Defeat all of the Horde Captains listed below within The Road of Glory.
Take Them Out is a 10-point achievement earned in Ashran by defeating all Horde Captains found along The Road of Glory.
Understand Captain Spawn Mechanics
Horde Captains spawn when the Alliance team reaches their enemy-slain objective counter. Once a captain spawns, the kill counter resets to zero and the next threshold increases, so captains become progressively harder to trigger as the match goes on.
Push The Road of Glory
Captains move toward whichever section of the road is currently being contested, behaving similarly to Kronus and Fangraal. The closer the Alliance pushes the contested flag toward the Horde base, the lower the Horde kill requirement becomes, making captains spawn more frequently.
Kill Vanguard Samuelle Immediately
When Vanguard Samuelle spawns, use 
Wand of Death on him immediately to kill him before he can bubble-hearth out of the area.
Tips
The Alliance kill counter and Horde kill counter are tracked separately and both displayed in the Ashran UI, so monitor the Alliance counter specifically to anticipate when Horde Captains will spawn.