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Enchantment I
Craft or enchant 100 times with the Enchanting profession.
Enchantment I requires crafting or enchanting 100 times using the Enchanting profession, and the fastest methods involve recycling shards or converting cheap materials into enchants.
Recycle Prismatic Shards
Buy around 50 
Large Prismatic Shards, then alternate between shattering them into 
Small Prismatic Shards and re-crafting them back into Large Prismatic Shards — this costs nothing net and you can spam the process using this macro with your Enchanting window open: /run local id = 28022; C_TradeSkillUI.CraftRecipe(id,C_TradeSkillUI.GetRecipeInfo(id).numAvailable) then /run local id = 42615; C_TradeSkillUI.CraftRecipe(id,C_TradeSkillUI.GetRecipeInfo(id).numAvailable). Pin both recipes as favorites so they appear at the top of your recipe list.
Craft With Draenic Dust
If you prefer an AFK-friendly approach, use Draenic Dust to craft Enchanted Dust — each craft costs only 1 dust, and if you have a large stockpile sitting in your bank, this method requires no Auction House trips.
Shatter Crystals for Profit
For a method that can turn a small profit, chain-shatter 
Eternal Crystal or 
Sha Crystal into dust, then use that dust to craft enchants — both the shatters and the enchant crafts count toward the 100 required for the achievement.
Craft Minor Health Spam
Alternatively, craft 2,000x Minor Health using 
Strange Dust, which is a straightforward if slow method that also counts toward the 100 crafts needed.