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Disenchantment I
Disenchant 50 items.
Disenchantment I requires you to disenchant 50 items using the Disenchanting profession skill.
Learn Disenchanting
Visit an Enchanting trainer and learn the Disenchanting skill if you do not already have it.
Collect enchantable items
Gather 50 items with an enchantable quality (typically uncommon, rare, or epic gear) through questing, dungeons, or the Auction House.
Disenchant the items
Open your spellbook, select Disenchant, and cast it on each of your 50 items to complete the achievement.