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Dueling Master
Win 50 duels in the Dueler's Guild.
Dueling Master requires winning 50 duels at the Dueler's Guild arena, rewarding the 
Dueler's Tabard upon completion.
Travel to Dueler's Guild
Head to the Dueler's Guild arena at 58.8, 26.2 and queue for duels. You will need Warmode enabled and must be on the same shard as your opponent to successfully queue.
Coordinate with Another Player
The Dueler's Guild arena is sparsely populated, so bringing a friend to duel against is the most reliable way to make progress. Being in the same group does not prevent you from queuing against each other.
Accumulate 50 Champion Wins
Each duel victory grants a stack of the Champion buff. You need 50 total counted wins for Dueling Master. Note that players level 110 and above can queue and their wins appear to count toward the achievement.
Tips
Winning 50 duels also satisfies the lower thresholds of Slugfest (5 wins) and Contender (25 wins) along the way, so all progress is shared across those achievements.