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Master of Duels
Complete the following Dueler's Guild achievements listed below.
Master of Duels is a meta-achievement requiring you to complete all Dueler's Guild sub-achievements, rewarding the Contender title upon completion.
Enable War Mode
Both you and your dueling partner must have War Mode enabled before queuing. Without it, you cannot participate in Dueler's Guild battles.
Travel to Boralus or Zuldazar
Alliance players head to Hook Point in Boralus, and Horde players go to Zuldazar. The Dueler's Guild arena is at 58.8, 26.2. Both dueling partners must be at least level 50 to queue.
Queue at the Bouncers or Troll Guards
Alliance players speak to the Bouncers at 58.8, 26.2 to queue for a duel. Horde players speak to the Troll Guards in Zuldazar. Use /tar Bouncer or /tar Troll Guard to locate them quickly.
Complete Your First Duel and Win
Queue and complete your first duel to earn Your First Duel: The First Rule of Dueler's Guild, then win a duel to earn Trial by Combat.
Win 3 Duels Without Leaving
Win 3 consecutive duels without leaving the arena to earn the Prize Fighter achievement. Having a cooperative partner lets you trade wins efficiently.
Earn Champion Milestones
Accumulate Champion wins by repeatedly dueling: 5 wins earns Slugfest, 25 wins earns Contender, and 50 wins earns Dueling Master along with the 
Dueler's Tabard.
Defeat Every Class: Thirty Six and Two
Defeat one player of each class in a duel to complete Thirty Six and Two. The fastest method is to have a friend create Class Trial characters (which start at level 50) across all required classes on the opposing faction, as Class Trials have access to the Zuldazar or Boralus portals needed to reach the arena at 58.8, 26.2.
Tips
Class Trial characters start at level 50 and have access to the Zuldazar/Boralus portal, making them ideal for completing Thirty Six and Two without needing to level multiple characters.